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Thread: VLE/LLE data regression in Properties

  1. #1

    VLE/LLE data regression in Properties

    I am doing VLE / LLE (vapor-liquid and liquid-liquid) data regression in P RODE PROPERTIES,
    input values are from Dortmund Data Bank,
    PRODE requires to specify X1, Y1, Temperature and Pressure,
    so for isothermal data sets I have the same pressure,
    the first column allows to specify VLE or LLE points,
    my question is, can I mix VLE and LLE equilibrium points ?
    The procedure finds a solution but I am not sure which is the range of application for these calculated BIPs

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  3. #2

    Re: VLE/LLE data regression in Properties

    that is possible,
    generally you can obtain some "average" values for BIPs
    which may produce a better fitting in processes where both
    VLE vapor-liquid-equilibria and LLE liquid-liquid-equilibria
    are present.
    By the way,
    once you have the BIPs
    you can calculate a TPXY
    or similar diagram to
    verify the range of application for that binary.

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  5. Re: VLE/LLE data regression in Properties

    stawad,
    I follow the same procedure,
    results (VLE fitting) are good.

  6. Re: VLE/LLE data regression in Properties

    make sure to select reliable VLE (or LLE) data,
    (some data sets are predicted not measured)

  7. #5

    Re: VLE/LLE data regression in Properties

    as confirmed by others you can mix
    VLE / LLE points in data regression utility,
    PRODE PROPERTIES allows to specify
    VLE vapor / liquid
    LLE liquid / liquid
    SLE solid / liquid
    equilibrium points

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