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Thread: Calculating entropy using an EOS

  1. Calculating entropy using an EOS

    Good morning,

    I am writing a code to simulating thermodynamic properties, like Winprop, and I am facing a problem in the entropy calculus.

    The main problem is, using a EOS is easy to calculate the excess entropy (In my case I am using PR equation), so the entropy is obtained adding the Ideal Gas Entropy:

    S = Excess_S + IG_S

    So my problem is to calculate the ideal gas entropy. I don't know if I have to calculate the pressure part of the equation, given by ln(p/pref). The thermodyinamical path chosen was the heating of the Ideal Gas, so I believe that the process is made a constant pressure and this term does not exist.

    If someone could help me I will be really thankful because I am stopped in this part.

    Thanks

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    Re: Calculating entropy using an EOS

    Hello. You can post your code here . Also describe the problem in details

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  5. Re: Calculating entropy using an EOS

    Quote Originally Posted by temr View Post
    Hello. You can post your code here . Also describe the problem in details
    Hello,

    I have solved my problem yesterday. In the Poling's book (Thermodynamical Properties), it is explained how to calculate the excess entropy of a real substance, and the software is now agreeing with NIST data.

    Thanks

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