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polytropic compression of wet gas with Prode Properties

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besides being a user of Prode Properties I work in a factory where there are several centrifugal compressors and I am interested to the different topics concerning design and rating of these complex machines,
I post a question about Polytropic Compression Of Wet Gas (Efficiency Evaluation) with Prode Properties and the answer given by PaoloPemi in Cheresources, it includes several examples which I think could be of interest for the readers

question
recently we changed the inlet spec's of our (two stages) centrifugal compressor (natural gas), now we have about 1% fraction of condensate (value estimated with both Peng Robinson or Soave thermo packages) at inlet,
the manufacturer said it's acceptable and we are reevaluating efficiency (and power consumption),
My questions concern the evaluation of polytropic efficiency in case of wet gas,
we have measured pressures, temperatures etc. and calculated the polytropic efficiency with Prode Properties (selecting the procedure for polytropic solution with phase equilibria), at the new operating condition the value is close to the original number (0.76) for dry gas (that could be Ok since we have only 1% condensate on inlet line and dry gas at outlet),

1) to improve the accuracy, should I attempt (and why) to evaluate directly (i.e. measure) the amount of condensate on inlet line?
Actually the liquid fraction is calculated by Prode with Peng Robinson model.

2) the outlet temperature estimated with the correlation for ideal gas tout = tin*(pout/pin)^(k*eff) is very different from the value calculated with Prode Properties (Prode calculates lower temperatures), I suppose it is Ok considering we have a pressure ratio of about 4 and some condensate to evaporate.

answer

I am not aware of standards discussing the calculation procedure to estimate the polytropic efficiency of a compressor under wet gas (gas + liquid) conditions,
for gas + different amounts of liquid I use the same procedure (Prode) to evaluate the efficiency,
in your case considering the low amount of condensate you may select the Huntington method (which is limited to dry gas) and see how much the results differ (you may be required to alter some value in order to have dry gas at inlet).
About phase equilibria at inlet condition I would presume that Peng Robinson can give reliable results.
Finally, according my experience it is quite usual to get higher temperatures (compared with rigorous procedures) with ideal gas correlation,

consider the case of methane compressed from 300K 10Bar.a to 40Bar.a

with efficiency = 1 (isentropic compression) the ideal gas model gives

cp/cv (tin,pin) = 1.3327 (Soave Redlich Kwong)
(k-1)/(k*eff) = 0.249
tout = tin*(pout/pin)^(k-1)/(k*eff) = 424K

with the rigorous model (see above) we get as tout = 409K

relative error (424-409)/(409-300) = 13%

now if we set a efficiency = 0.5 we get

(k-1)/(k*eff) = 0.499
tout = tin*(pout/pin)^(k-1)/(k*eff) = 599K

with the rigorous model (see above) we get as tout = 525.7K

relative error (599-525.7)/(525.7-300) = 33%

now if we add the contribute of phase equilibria (polytropic solution with phase equilibria model) we can observe large differences in tout-tin mainly due to the contribute of enthalpy of vaporization,

consider the case of the mixture methane 0.8 n-Butane 0.2 (molar fractions) compressed from 10Bar.a to 40Bar.a
with a polytropic efficiency = 0.75 , model Peng-Robinson

this mixture has a dew point of 287.9 at 10Bar.a then at 288K is in vapor phase
with the polytropic solution with phase equilibria starting from 288K @ 10 Bar.a we get as tout = 393K

at 272.47K 10Bar.a the mixture shows a liquid fraction = 0.1
with the polytropic solution with phase equilibria starting from 272.46K @ 10 Bar.a we get as tout = 337.5K

if we compare the values of tout-tin we get 105K in the first case (all gas) and 65.04K in the second case (with 10% liquid molar fraction at inlet condition)
a quite large difference,
in your case the liquid fraction is very small but it has certainly some influence.

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